Discrete Event Modeling and Simulation for IoT Efficient Design Combining WComp and DEVSimPy Framework

International audienceOne of today's challenges in the framework of ubiquitous computing concerns the design of ambient systems including sensors, smart-phones, interconnected objects, computers, etc. The major difficulty is to propose a compositional adaptation which aims to integrate new features that were not foreseen in the design, remove or exchange entities that are no longer available in a given context. In order to provide help to overcome this difficulty, a new approach based on the definition of strategies validated using discrete-event simulation is proposed. Such strategies make it possible to take into account conflicts and compositional adaptation of components in ambient systems. These are defined and validate using a discrete-event formalism to be integrated into a prototyping and dynamic execution environment for ambient intelligence applications. The proposed solution allows the designers of ambient systems to define the optimum matching of all components to each other. One pedagogical example is presented (switch-lamp system) as a proof of the proposed approach

Fe(III)-Citrate-Complex-Induced Photooxidation of 3-Methylphenol in Aqueous Solution

The photodegradation process of m-cresol (3-methylphenol), induced by Fe(III)-Cit complex, was investigated upon irradiation at 365 nm in natural water. The composition and photochemical properties of Fe(III)-Cit complex were studied by UV-Visible absorption spectrophotometer for optimizing the stoichiometry of the complex and photolysis under irradiation at 365 nm, respectively. A dark investigation of the system was performed before studying the photochemical behavior. The photooxidation efficiencies of m-cresol were dependent on the pH value, optimized at pH 2.86, oxygen, initial concentrations of Fe(III)-Cit complex, and m-cresol. Additionally, to look into the mechanism of m-cresol degradation using Fe(III)-Cit, tertiobutanol alcohol was used as scavenger for hydroxyl radicals and the result suggested that hydroxyl radical attack was the main pathway of m-cresol degradation. Besides, oxygen can enhance the photolysis of Fe(III)-Citrate complex by trapping the electron on the carbon centered radical formed after the photoredox process. Then O •− 2 formed reacts rapidly leading finally to formation of • OH radical. In absence of oxygen, less reactive species are formed; consequently the disappearance of m-cresol was strongly inhibited. Our work shows that the presence of Fe(III)-Citrate complex could have a considerable impact on the fate of organic pollutant in aquatic environment

An Efficient Green Photo-Fenton System for the Degradation of Organic Pollutants. Kinetics of Propranolol Removal From Different Water Matrices

Financiado para publicación en acceso aberto: Universidade da Coruña/CISUG[Abstract] We report on the degradation of aqueous propranolol (PRO) in a heterogeneous system with natural iron oxide (N.I.O.) and oxalic acid (OAA) under near UV–Vis irradiation. Photolysis experiments showed ca. 65% degradation of PRO after 2 h irradiation, and a similar degradation in the presence of N.I.O. A more efficient PRO removal was obtained upon irradiation within a mixture of N.I.O. and OAA. Under the best conditions considered, complete degradation (> 95%) was observed in less than 10 min, and TOC decreased by 60% after 3 h irradiation. The observed processes were adequately fitted by pseudo-first-order kinetics, the corresponding rate constants were determined, and the effect of different variables analyzed. Photodegradation of PRO is accelerated under acidic conditions, and neutralization takes place along the reaction. Hydroxyl radicals play a predominant role in the photodegradation reaction, as shown by the dramatic inhibition observed upon t-butanol addition. Furthermore, HOradical dot formation is strongly dependent on the pH of the medium. LC-MS identification of ten different intermediates leads to the proposal of a degradation mechanism. This photocatalytic system has also proven effective, for the first time, in different real aqueous matrices (river water > distilled water > sewage ≫ > seawater, revealing quite efficient in the former) and also employing sunlight, where PRO photodegradation was slower. The results obtained show that N.I.O.-oxalate complexes are a green, cheap choice for removing organic pollutants in aqueous solution.The authors acknowledge the financial support of the Ministry of Higher Education and Scientific Research of Algeria (Project B00L01UN250120210003) and for research visits of WR and HB to UDC. This research was partially supported by the React! Group at UDC, and funded by the Spanish Ministerio de Economía y Competitividad through project CTQ2015-71238-R (MINECO/FEDER), and the Xunta de Galicia (Project GPC ED431B 2020/52), respectively. Funding for open access publication was provided by Universidade da Coruña/CISUGArgelia. Ministre de l'Enseignement Supérieur et de la Recherche Scientifique; B00L01UN250120210003Xunta de Galicia; ED431B 2020/5

FEBUKO and MODMEP: Field measurements and modelling of aerosol and cloud multiphase processes

An overview of the two FEBUKO aerosol–cloud interaction field experiments in the Thüringer Wald (Germany) in October 2001 and 2002 and the corresponding modelling project MODMEP is given. Experimentally, a variety of measurement methods were deployed to probe the gas phase, particles and cloud droplets at three sites upwind, downwind and within an orographic cloud with special emphasis on the budgets and interconversions of organic gas and particle phase constituents. Out of a total of 14 sampling periods within 30 cloud events three events (EI, EII and EIII) are selected for detailed analysis. At various occasions an impact of the cloud process on particle chemical composition such as on the organic compounds content, sulphate and nitrate and also on particle size distributions and particle mass is observed. Moreover, direct phase transfer of polar organic compound from the gas phase is found to be very important for the understanding of cloudwater composition. For the modelling side, a main result of the MODMEP project is the development of a cloud model, which combines a complex multiphase chemistry with detailed microphysics. Both components are described in a fine-resolved particle/drop spectrum. New numerical methods are developed for an efficient solution of the entire complex model. A further development of the CAPRAM mechanism has lead to a more detailed description of tropospheric aqueous phase organic chemistry. In parallel, effective tools for the reduction of highly complex reaction schemes are provided. Techniques are provided and tested which allow the description of complex multiphase chemistry and of detailed microphysics in multidimensional chemistry-transport models

Fe(III)-enhanced, sonochemical degradation, photodegradatin and photocatalysis of isoproturon in aqueous solution or suspension ; analytic and kinetic study

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